Corrosion

Corrosion:

  • Corrosion is the gradual deterioration of metals due to their reaction with environmental factors such as oxygen, moisture, and pollutants.
  • Example: Rusting of iron.

Causes of Corrosion:

  • Presence of Moisture: Water in the environment facilitates the oxidation of metals.
  • Oxygen: Combines with metals to form oxides.
  • Pollutants: Gases like sulfur dioxide and carbon dioxide accelerate corrosion.

Examples of Corrosion:

  • Iron: Rusts to form hydrated ferric oxide (Fe₂O₃·xH₂O).
  • Copper: Forms a green layer of basic copper carbonate (patina).
  • Silver: Tarnishes to form silver sulfide (Ag₂S).
  • Aluminium: Forms a protective layer of aluminium oxide (Al₂O₃).

Rusting of Iron:

  • Reaction: 4Fe + 3O₂ + 6H₂O → 4Fe(OH)₃, which dehydrates to Fe₂O₃·xH₂O (rust).
  • Rusting is a specific type of corrosion that weakens iron structures.

Factors Affecting Corrosion:

  • Humidity: High moisture levels increase corrosion.
  • Temperature: Higher temperatures accelerate chemical reactions.
  • Impurities: Saltwater and acidic pollutants enhance corrosion rates.

Prevention of Corrosion:

  • Coating and Painting: Creates a protective barrier against moisture and air.
  • Galvanization: Coating iron with a layer of zinc.
  • Alloying: Mixing metals to improve corrosion resistance (e.g., stainless steel).
  • Electroplating: Depositing a layer of a less reactive metal on the surface.
  • Cathodic Protection: Using a more reactive metal as a sacrificial anode to protect the main metal.
  • Greasing or Oiling: Prevents moisture contact with the metal surface.

Impact of Corrosion:

  • Weakens metal structures, reducing their strength and durability.
  • Causes economic loss due to the replacement and maintenance of corroded materials.
  • Leads to safety hazards, especially in bridges, buildings, and pipelines.

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