Extraction Of Metals From The Ores

  • Ores are naturally occurring rocks or minerals containing sufficient quantities of metal for economic extraction.
  • Concentration of Ore: Removal of impurities (gangue) to increase the metal concentration.
    • Methods include:
      • Froth Flotation: For sulfide ores like copper.
      • Magnetic Separation: For ores like hematite (iron).
      • Gravity Separation: For denser ore particles.
  • Extraction of Metal:
    • Metals are extracted depending on their position in the reactivity series.
  • Purification of Metal: Removing impurities to obtain pure metal.
  • Highly Reactive Metals:
    • Extracted via Electrolysis.
    • Example: Aluminium from bauxite (Al₂O₃·2H₂O).
  • Moderately Reactive Metals:
    • Reduced using carbon or carbon monoxide.
    • Example: Iron from hematite (Fe₂O₃) using a blast furnace.
  • Less Reactive Metals:
    • Found in the free state or reduced by simple methods.
    • Example: Gold, silver.
  • Reduction by Carbon:
    • Used for metals like iron.
    • Reaction: Fe₂O₃ + 3CO → 2Fe + 3CO₂.
  • Electrolytic Reduction:
    • Used for metals like sodium, potassium, and aluminium.
    • Reaction: 2Al₂O₃ → 4Al + 3O₂ (in a molten state).
  • Thermal Decomposition:
    • For less stable ores.
    • Example: 2HgO → 2Hg + O₂.
  • Inputs: Iron ore, coke, and limestone.
  • Outputs: Molten iron and slag (waste material).
  • Reaction:
    • Formation of CO: C + O₂ → CO₂; CO₂ + C → 2CO.
    • Reduction of iron ore: Fe₂O₃ + 3CO → 2Fe + 3CO₂.
  • Impure metals are purified using Electrolytic Refining.
    • Example: Copper refining.
    • Impure copper is the anode; pure copper collects at the cathode.
  • Mining and extraction lead to habitat destruction, pollution, and energy use.
  • Recycling and sustainable methods can minimize environmental impact.

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