Thermal Equilibrium – Heat And Temperature

  • Heat is a form of energy that is transferred from a hotter object to a cooler one. It flows due to the difference in temperature between two bodies.
  • Temperature is the measure of the average kinetic energy of the particles in an object. It determines how hot or cold an object is.
  • Heat:
    • Measured in joules (J).
    • Represents the total energy of molecular motion in a substance.
    • Heat flows from a region of high temperature to a region of low temperature.
  • Temperature:
    • Measured in Celsius (°C), Kelvin (K), or Fahrenheit (°F).
    • Represents the average kinetic energy of the particles in a substance.
    • Does not depend on the amount of substance but on its thermal state.
  • Thermal equilibrium occurs when two bodies are in contact and there is no net flow of heat between them. This means both bodies are at the same temperature.
    • When thermal equilibrium is reached, the heat energy transferred between the bodies becomes zero because the temperatures are the same.
  • The Zeroth Law of Thermodynamics states that:
    • If two bodies are each in thermal equilibrium with a third body, then they are in thermal equilibrium with each other.
    • This principle allows the definition of temperature. It implies that temperature is a fundamental property that determines whether two bodies are in thermal equilibrium.
    • Example: If object A is in thermal equilibrium with object B, and object B is in thermal equilibrium with object C, then object A is in thermal equilibrium with object C.
  • Heat can be transferred in three main ways:
  • Conduction:
    • Transfer of heat through direct contact between particles in a substance.
    • Occurs in solids, where particles vibrate and pass on heat energy.
    • Example: Heat flowing through a metal rod.
  • Convection:
    • Transfer of heat through the movement of fluids (liquids and gases).
    • Occurs when warmer parts of a fluid rise and cooler parts sink, creating a cycle.
    • Example: Warm air rising near a heater, or water heating in a pot.
  • Radiation:
    • Transfer of heat in the form of electromagnetic waves (infrared radiation).
    • Does not require a medium (can happen in a vacuum).
    • Example: Heat from the Sun reaching Earth.
  • Thermometers are used to measure temperature.
    • Mercury thermometers: Use mercury that expands and contracts with temperature.
    • Digital thermometers: Use electronic sensors to measure temperature.
    • Thermometers in everyday life measure the temperature of air, water, and objects.
  • Temperature can be measured in different scales:
    • Celsius (°C): Freezing point of water is 0°C and boiling point is 100°C.
    • Kelvin (K): Used in scientific contexts. The absolute zero is 0 K (-273.15°C).
    • Fahrenheit (°F): Used mainly in the United States. Freezing point of water is 32°F, and boiling point is 212°F.
  • Specific heat capacity is the amount of heat required to raise the temperature of 1 kg of a substance by 1°C (or 1 K).
  • The formula for specific heat capacity is: Q=mcΔTQ ,where:
  • Water has a high specific heat capacity, meaning it can absorb a lot of heat before its temperature rises significantly, making it a good coolant.
  • Latent heat is the amount of heat required to change the phase of a substance without changing its temperature.
    • Latent heat of fusion: Heat required to convert a solid into a liquid (e.g., melting ice).
    • Latent heat of vaporization: Heat required to convert a liquid into a gas (e.g., boiling water).
  • Formula for Latent Heat: Q=mLQ = mL where:
    • Q is the heat energy (in joules).
    • m is the mass of the substance (in kg).
    • L is the latent heat (in J/kg).
  • Thermal Insulation:
    • Materials like wool, fiberglass, and polystyrene are used to reduce heat transfer and keep buildings warm in winter and cool in summer.
  • Engineering:
    • Concepts of heat transfer and thermal equilibrium are important in designing engines, refrigerators, and heat exchangers.
  • Daily Life:
    • Cooking, cooling systems, air conditioning, and the design of electrical devices rely on principles of heat and temperature.
  • Heat and temperature are essential concepts in understanding how energy is transferred in different systems.
  • Thermal equilibrium is the state in which two objects in contact no longer exchange heat because they have reached the same temperature.
  • Understanding how heat is transferred (conduction, convection, and radiation) and how substances respond to heat (specific heat and latent heat) is critical in real-life applications and scientific phenomena.

Let’s practice!